Barbara was born and raised in Florida. She attended Florida State University, where she earned her bachelor’s degree in 1952 and her master’s degree in 1954.
She began her teaching career as an English literature instructor at Miami Jackson High school in 1954.
At the beginning of her career, the school’s student body was 90% white middle-class students. In 1963, in response to the 1954 Supreme Court ruling Brown vs. Board of Education which prohibited segregation in schools, Florida began to admit black students to white schools. By 1966, the student body at Miami Jackson High was 85% African American, predominantly from impoverished families. To respond to the needs of this new student population, Barbara helped develop innovative instructional programs and demonstrated a nurturing attitude toward students. For her efforts, she was recognized with the National Teacher of the Year Award in 1969. She was the first Southerner in eighteen years to be so honored. President Richard Nixon presented the award to Barbara in a White House ceremony.
In 1975, Barbara transferred to North Miami Beach Senior High School as a teacher and staff development specialist for internship programs. Ten years later, she became an administrator for Language Arts at the District Office.
This remarkable educator retired in 1990. Barbara Goleman High School, opened in 1995, was named in her honor. It was the first school in Miami-Dade County to be named after one of its teachers.